I could use 3 aquastats, one to watch outside temp (double throw), and switch between the other aquastats, each with different settings to enable the backup heating system depending on the tank temp.
say, below 15 or 20 degrees outside temp, aquastat 1 is enabling aquastat 2, which enables the backup system when tank temp (primary loop temp?) drops below 130 deg for the furnace fan coil. when the outside temp is above 20 deg, it enables the backup system when the tank temp drops below 120, or wherever it won't satisfy the heating load. Crude, but it'd work. Requiring a lot of fiddling to set up though. good for the tinkerer.
of course in a simple heating system control scenario, (like furnace fan coil) it'd probably be easiest to use a 2 stage thermostat. upper setpoint enables garn heat, and disables the burner, 2nd stage disables garn pump and enables the burner.
boiler controls, multiple zoning is so much more fun.
Karl